A facile one-pot synthesis of meso-aryl-substituted [14]triphyrin(2.1.1)

Zhao Li Xue; Zhen Shen; John Mack; Daiki Kuzuhara; Hiroko Yamada; Tetsuo Okujima; Noboru Ono; Xiao Zeng You; Nagao Kobayashi

doi:10.1021/ja8068769

A facile one-pot synthesis of meso-aryl-substituted [14]triphyrin(2.1.1)

Zhao Li Xue, Zhen Shen, John Mack, Daiki Kuzuhara, Hiroko Yamada, Tetsuo Okujima, Noboru Ono, Xiao Zeng You, Nagao Kobayashi

Research output: Contribution to journal › Article › peer-review

97 Citations (Scopus)

Abstract

The synthesis and spectroscopic properties of a series of boron-free meso-aryl-substituted [14]triphyrin(2.1.1) compounds containing either peripheral bicyclo[2.2.2]octadiene (BCOD) (2a-c) or benzene rings (3a-c) (aryl = phenyl a, 4-fluorophenyl b, and 4-methylbenzoatephenyl c) are reported. These compounds represent the first examples of free-base contracted porphyrinoids with 14 π-electron aromatic systems containing only the standard pyrrole and isoindoline moieties of the porphyrins and tetrabenzoporphyrins.

Original language	English
Pages (from-to)	16478-16479
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	130
Issue number	49
DOIs	https://doi.org/10.1021/ja8068769
Publication status	Published - 2008 Dec 10

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja8068769

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A facile one-pot synthesis of meso-aryl-substituted [14]triphyrin(2.1.1). / Xue, Zhao Li; Shen, Zhen; Mack, John; Kuzuhara, Daiki; Yamada, Hiroko; Okujima, Tetsuo; Ono, Noboru; You, Xiao Zeng; Kobayashi, Nagao.

In: Journal of the American Chemical Society, Vol. 130, No. 49, 10.12.2008, p. 16478-16479.

Research output: Contribution to journal › Article › peer-review

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AU - Yamada, Hiroko

AU - Okujima, Tetsuo

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A facile one-pot synthesis of meso-aryl-substituted [14]triphyrin(2.1.1)

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