A facile one-pot synthesis of meso-aryl-substituted [14]triphyrin(2.1.1)

Zhao Li Xue; Zhen Shen; John Mack; Daiki Kuzuhara; Hiroko Yamada; Tetsuo Okujima; Noboru Ono; Xiao Zeng You; Nagao Kobayashi

doi:10.1021/ja8068769

A facile one-pot synthesis of meso-aryl-substituted [14]triphyrin(2.1.1)

Zhao Li Xue, Zhen Shen, John Mack, Daiki Kuzuhara, Hiroko Yamada, Tetsuo Okujima, Noboru Ono, Xiao Zeng You, Nagao Kobayashi

Research output: Contribution to journal › Article › peer-review

86 Citations (Scopus)

Abstract

The synthesis and spectroscopic properties of a series of boron-free meso-aryl-substituted [14]triphyrin(2.1.1) compounds containing either peripheral bicyclo[2.2.2]octadiene (BCOD) (2a-c) or benzene rings (3a-c) (aryl = phenyl a, 4-fluorophenyl b, and 4-methylbenzoatephenyl c) are reported. These compounds represent the first examples of free-base contracted porphyrinoids with 14 π-electron aromatic systems containing only the standard pyrrole and isoindoline moieties of the porphyrins and tetrabenzoporphyrins.

Original language	English
Pages (from-to)	16478-16479
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	130
Issue number	49
DOIs	https://doi.org/10.1021/ja8068769
Publication status	Published - 2008 Dec 10

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

Access to Document

10.1021/ja8068769

Fingerprint Dive into the research topics of 'A facile one-pot synthesis of meso-aryl-substituted [14]triphyrin(2.1.1)'. Together they form a unique fingerprint.

Cite this

A facile one-pot synthesis of meso-aryl-substituted [14]triphyrin(2.1.1). / Xue, Zhao Li; Shen, Zhen; Mack, John; Kuzuhara, Daiki; Yamada, Hiroko; Okujima, Tetsuo; Ono, Noboru; You, Xiao Zeng; Kobayashi, Nagao.

In: Journal of the American Chemical Society, Vol. 130, No. 49, 10.12.2008, p. 16478-16479.

Research output: Contribution to journal › Article › peer-review

@article{c0c72d4ac04f40a99a8be95d936a47bd,

title = "A facile one-pot synthesis of meso-aryl-substituted [14]triphyrin(2.1.1)",

abstract = "The synthesis and spectroscopic properties of a series of boron-free meso-aryl-substituted [14]triphyrin(2.1.1) compounds containing either peripheral bicyclo[2.2.2]octadiene (BCOD) (2a-c) or benzene rings (3a-c) (aryl = phenyl a, 4-fluorophenyl b, and 4-methylbenzoatephenyl c) are reported. These compounds represent the first examples of free-base contracted porphyrinoids with 14 π-electron aromatic systems containing only the standard pyrrole and isoindoline moieties of the porphyrins and tetrabenzoporphyrins.",

author = "Xue, {Zhao Li} and Zhen Shen and John Mack and Daiki Kuzuhara and Hiroko Yamada and Tetsuo Okujima and Noboru Ono and You, {Xiao Zeng} and Nagao Kobayashi",

year = "2008",

month = dec,

day = "10",

doi = "10.1021/ja8068769",

language = "English",

volume = "130",

pages = "16478--16479",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "49",

}

TY - JOUR

T1 - A facile one-pot synthesis of meso-aryl-substituted [14]triphyrin(2.1.1)

AU - Xue, Zhao Li

AU - Shen, Zhen

AU - Mack, John

AU - Kuzuhara, Daiki

AU - Yamada, Hiroko

AU - Okujima, Tetsuo

AU - Ono, Noboru

AU - You, Xiao Zeng

AU - Kobayashi, Nagao

PY - 2008/12/10

Y1 - 2008/12/10

N2 - The synthesis and spectroscopic properties of a series of boron-free meso-aryl-substituted [14]triphyrin(2.1.1) compounds containing either peripheral bicyclo[2.2.2]octadiene (BCOD) (2a-c) or benzene rings (3a-c) (aryl = phenyl a, 4-fluorophenyl b, and 4-methylbenzoatephenyl c) are reported. These compounds represent the first examples of free-base contracted porphyrinoids with 14 π-electron aromatic systems containing only the standard pyrrole and isoindoline moieties of the porphyrins and tetrabenzoporphyrins.

AB - The synthesis and spectroscopic properties of a series of boron-free meso-aryl-substituted [14]triphyrin(2.1.1) compounds containing either peripheral bicyclo[2.2.2]octadiene (BCOD) (2a-c) or benzene rings (3a-c) (aryl = phenyl a, 4-fluorophenyl b, and 4-methylbenzoatephenyl c) are reported. These compounds represent the first examples of free-base contracted porphyrinoids with 14 π-electron aromatic systems containing only the standard pyrrole and isoindoline moieties of the porphyrins and tetrabenzoporphyrins.

UR - http://www.scopus.com/inward/record.url?scp=57549099403&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=57549099403&partnerID=8YFLogxK

U2 - 10.1021/ja8068769

DO - 10.1021/ja8068769

M3 - Article

C2 - 19049444

AN - SCOPUS:57549099403

VL - 130

SP - 16478

EP - 16479

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 49

ER -

A facile one-pot synthesis of meso-aryl-substituted [14]triphyrin(2.1.1)

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Cite this