A facile one-pot synthesis of meso-aryl-substituted [14]triphyrin(2.1.1)

Zhao Li Xue, Zhen Shen, John Mack, Daiki Kuzuhara, Hiroko Yamada, Tetsuo Okujima, Noboru Ono, Xiao Zeng You, Nagao Kobayashi

Research output: Contribution to journalArticlepeer-review

86 Citations (Scopus)

Abstract

The synthesis and spectroscopic properties of a series of boron-free meso-aryl-substituted [14]triphyrin(2.1.1) compounds containing either peripheral bicyclo[2.2.2]octadiene (BCOD) (2a-c) or benzene rings (3a-c) (aryl = phenyl a, 4-fluorophenyl b, and 4-methylbenzoatephenyl c) are reported. These compounds represent the first examples of free-base contracted porphyrinoids with 14 π-electron aromatic systems containing only the standard pyrrole and isoindoline moieties of the porphyrins and tetrabenzoporphyrins.

Original languageEnglish
Pages (from-to)16478-16479
Number of pages2
JournalJournal of the American Chemical Society
Volume130
Issue number49
DOIs
Publication statusPublished - 2008 Dec 10

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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