A discrete conglomerate of a distorted Mo(v)-porphyrin with a directly coordinated keggin-type polyoxometalate

Atsutoshi Yokoyama, Takahiko Kojima, Kei Ohkubo, Shunichi Fukuzumi

    Research output: Contribution to journalArticlepeer-review

    69 Citations (Scopus)

    Abstract

    The reaction of a saddle-distorted Mo(v)-dodecaphenylporphyrin complex and a Keggin-type polyoxometalate gives a discrete and nanosized molecule, [{Mo(DPP)(O)}2(H2SiW12O40)], which involves direct coordination between the Mo(v) centers and terminal oxo groups of the polyoxometalate and exhibits excellent stability in solution to show reversible multi-redox processes.

    Original languageEnglish
    Pages (from-to)3997-3999
    Number of pages3
    JournalChemical Communications
    Issue number39
    DOIs
    Publication statusPublished - 2007

    ASJC Scopus subject areas

    • Catalysis
    • Electronic, Optical and Magnetic Materials
    • Ceramics and Composites
    • Chemistry(all)
    • Surfaces, Coatings and Films
    • Metals and Alloys
    • Materials Chemistry

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