A dinuclear ruthenium(II) chelating amido complex: Synthesis, characterization, and coupling reaction with carbon monoxide

Shin Takemoto, Shinya Oshio, Tomoharu Kobayashi, Hiroyuki Matsuzaka, Masatsugu Hoshi, Hironobu Okimura, Masayo Yamashita, Hitoshi Miyasaka, Tomohiko Ishii, Masahiro Yamashita

Research output: Contribution to journalArticlepeer-review

20 Citations (Scopus)

Abstract

[Cp*RuCl]4 (Cp* = η5-C 5Me5) reacts with 2 equiv of dilithium 2,3-naphthalenediamide to afford the dinuclear bridging amido complex [(Cp*Ru)22-(NH)2- C 10H6}] (1b) in moderate yield. Treatment of 1b with CO (1 atm) resulted in the incorporation of three molecules of CO into the diruthenium core to give the carbamoyl amido bis(carbonyl) complex [Cp*Ru([μ2-CO)-{μ2-2,3-(CONH)(NH)C 10H6}RuCp*(CO)] (4).

Original languageEnglish
Pages (from-to)3587-3589
Number of pages3
JournalOrganometallics
Volume23
Issue number15
DOIs
Publication statusPublished - 2004 Jul 19
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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