A dimer-of-dimers composed of paddlewheel diruthenium(II, III) complexes and a bridge of tetrachlorohydroquinonate(2-) derived by intramolecular charge transfers

Masahisa Itoh; Yuichiro Asai; Hiromichi Kamo; Akira Miura; Hitoshi Miyasaka

doi:10.1246/cl.2012.26

A dimer-of-dimers composed of paddlewheel diruthenium(II, III) complexes and a bridge of tetrachlorohydroquinonate(2-) derived by intramolecular charge transfers

Masahisa Itoh, Yuichiro Asai, Hiromichi Kamo, Akira Miura, Hitoshi Miyasaka

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The reaction of a paddlewheel-type diruthenium(II, II) complex, [Ru ₂ ^II,II(o-MeOPhCO ₂) ₄(THF) ₂] ([Ru ₂ ^II,II]; o-MeOPhCO ₂-: o-anisate), and chloranil (QCl ₄) leads to a charge transfer from [Ru ₂ ^II,II] to QCl ₄, forming a dimer-of-dimers of [Ru ₂ ^II,III]+ units bridged by tetrachlorohydroquinonate dianion (QCl ₄ ²-): [{Ru ₂ ^II,III(o-MeOPhCO ₂) ₄(THF)} ₂(QCl ₄)].

Original language	English
Pages (from-to)	26-28
Number of pages	3
Journal	Chemistry Letters
Volume	41
Issue number	1
DOIs	https://doi.org/10.1246/cl.2012.26
Publication status	Published - 2012
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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title = "A dimer-of-dimers composed of paddlewheel diruthenium(II, III) complexes and a bridge of tetrachlorohydroquinonate(2-) derived by intramolecular charge transfers",

abstract = "The reaction of a paddlewheel-type diruthenium(II, II) complex, [Ru 2 II,II(o-MeOPhCO 2) 4(THF) 2] ([Ru 2 II,II]; o-MeOPhCO 2-: o-anisate), and chloranil (QCl 4) leads to a charge transfer from [Ru 2 II,II] to QCl 4, forming a dimer-of-dimers of [Ru 2 II,III]+ units bridged by tetrachlorohydroquinonate dianion (QCl 4 2-): [{Ru 2 II,III(o-MeOPhCO 2) 4(THF)} 2(QCl 4)].",

author = "Masahisa Itoh and Yuichiro Asai and Hiromichi Kamo and Akira Miura and Hitoshi Miyasaka",

year = "2012",

doi = "10.1246/cl.2012.26",

language = "English",

volume = "41",

pages = "26--28",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Chemical Society of Japan",

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T1 - A dimer-of-dimers composed of paddlewheel diruthenium(II, III) complexes and a bridge of tetrachlorohydroquinonate(2-) derived by intramolecular charge transfers

AU - Itoh, Masahisa

AU - Asai, Yuichiro

AU - Kamo, Hiromichi

AU - Miura, Akira

AU - Miyasaka, Hitoshi

PY - 2012

Y1 - 2012

N2 - The reaction of a paddlewheel-type diruthenium(II, II) complex, [Ru 2 II,II(o-MeOPhCO 2) 4(THF) 2] ([Ru 2 II,II]; o-MeOPhCO 2-: o-anisate), and chloranil (QCl 4) leads to a charge transfer from [Ru 2 II,II] to QCl 4, forming a dimer-of-dimers of [Ru 2 II,III]+ units bridged by tetrachlorohydroquinonate dianion (QCl 4 2-): [{Ru 2 II,III(o-MeOPhCO 2) 4(THF)} 2(QCl 4)].

AB - The reaction of a paddlewheel-type diruthenium(II, II) complex, [Ru 2 II,II(o-MeOPhCO 2) 4(THF) 2] ([Ru 2 II,II]; o-MeOPhCO 2-: o-anisate), and chloranil (QCl 4) leads to a charge transfer from [Ru 2 II,II] to QCl 4, forming a dimer-of-dimers of [Ru 2 II,III]+ units bridged by tetrachlorohydroquinonate dianion (QCl 4 2-): [{Ru 2 II,III(o-MeOPhCO 2) 4(THF)} 2(QCl 4)].

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A dimer-of-dimers composed of paddlewheel diruthenium(II, III) complexes and a bridge of tetrachlorohydroquinonate(2-) derived by intramolecular charge transfers

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