A cyanido-bridged luminescent coordination polymer composed of janus-type layers and its two-dimensional negative thermal expansion

Kenta Sasaki; Haruka Yoshino; Jingo Kitano; Benjamin Le Ouay; Ryo Ohtani; Masaaki Ohba

doi:10.1246/cl.210244

A cyanido-bridged luminescent coordination polymer composed of janus-type layers and its two-dimensional negative thermal expansion

Kenta Sasaki, Haruka Yoshino, Jingo Kitano, Benjamin Le Ouay, Ryo Ohtani, Masaaki Ohba

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

A luminescent two-dimensional coordination polymer of type [Cd(H₂O)(EtOH)][ReN(CN)₄(H₂O)]¢2H₂O (CdRe) incorporating “Janus-type” cyanido-bridged layers was synthesized. Within each layer of CdRe, the asymmetric [ReN(CN)₄]²¹ units are arranged so that all nitrides are oriented in the same direction. Moreover, Cd ions also have an asymmetric coordination structure, with ethanol being bound axially on the nitride side, and water on the opposite side. Layers are then stacked in a head-to-head manner, defining a succession of hydrophilic and hydrophobic interlayer domains. CdRe exhibits anisotropic thermal expansion including in-plane negative and out-of-plane positive thermal expansion behavior, and shows green emission (_em = 509 nm) originating from the metal-centered dd transition of [ReN(CN)₄]²¹ units.

Original language	English
Pages (from-to)	1577-1580
Number of pages	4
Journal	Chemistry Letters
Volume	50
Issue number	8
DOIs	https://doi.org/10.1246/cl.210244
Publication status	Published - 2021 Aug
Externally published	Yes

Keywords

Coordination polymer
Luminescence
Thermal expansion

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.210244

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@article{389f0f6cbc624608af3589bc974aa696,

title = "A cyanido-bridged luminescent coordination polymer composed of janus-type layers and its two-dimensional negative thermal expansion",

abstract = "A luminescent two-dimensional coordination polymer of type [Cd(H2O)(EtOH)][ReN(CN)4(H2O)]¢2H2O (CdRe) incorporating “Janus-type” cyanido-bridged layers was synthesized. Within each layer of CdRe, the asymmetric [ReN(CN)4]21 units are arranged so that all nitrides are oriented in the same direction. Moreover, Cd ions also have an asymmetric coordination structure, with ethanol being bound axially on the nitride side, and water on the opposite side. Layers are then stacked in a head-to-head manner, defining a succession of hydrophilic and hydrophobic interlayer domains. CdRe exhibits anisotropic thermal expansion including in-plane negative and out-of-plane positive thermal expansion behavior, and shows green emission (em = 509 nm) originating from the metal-centered dd transition of [ReN(CN)4]21 units.",

keywords = "Coordination polymer, Luminescence, Thermal expansion",

author = "Kenta Sasaki and Haruka Yoshino and Jingo Kitano and {Le Ouay}, Benjamin and Ryo Ohtani and Masaaki Ohba",

note = "Funding Information: This work was supported by the JSPS KAKENHI Grant Number JP16H06519, JP18H01997, JP18K14245, JP19H04701 and JP20K22554 as well as JSPS Research Fellowships for Young scientists Number JP19J12589. Publisher Copyright: {\textcopyright} 2021 Chemical Society of Japan. All rights reserved.",

year = "2021",

month = aug,

doi = "10.1246/cl.210244",

language = "English",

volume = "50",

pages = "1577--1580",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Chemical Society of Japan",

number = "8",

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TY - JOUR

T1 - A cyanido-bridged luminescent coordination polymer composed of janus-type layers and its two-dimensional negative thermal expansion

AU - Sasaki, Kenta

AU - Yoshino, Haruka

AU - Kitano, Jingo

AU - Le Ouay, Benjamin

AU - Ohtani, Ryo

AU - Ohba, Masaaki

N1 - Funding Information: This work was supported by the JSPS KAKENHI Grant Number JP16H06519, JP18H01997, JP18K14245, JP19H04701 and JP20K22554 as well as JSPS Research Fellowships for Young scientists Number JP19J12589. Publisher Copyright: © 2021 Chemical Society of Japan. All rights reserved.

PY - 2021/8

Y1 - 2021/8

N2 - A luminescent two-dimensional coordination polymer of type [Cd(H2O)(EtOH)][ReN(CN)4(H2O)]¢2H2O (CdRe) incorporating “Janus-type” cyanido-bridged layers was synthesized. Within each layer of CdRe, the asymmetric [ReN(CN)4]21 units are arranged so that all nitrides are oriented in the same direction. Moreover, Cd ions also have an asymmetric coordination structure, with ethanol being bound axially on the nitride side, and water on the opposite side. Layers are then stacked in a head-to-head manner, defining a succession of hydrophilic and hydrophobic interlayer domains. CdRe exhibits anisotropic thermal expansion including in-plane negative and out-of-plane positive thermal expansion behavior, and shows green emission (em = 509 nm) originating from the metal-centered dd transition of [ReN(CN)4]21 units.

AB - A luminescent two-dimensional coordination polymer of type [Cd(H2O)(EtOH)][ReN(CN)4(H2O)]¢2H2O (CdRe) incorporating “Janus-type” cyanido-bridged layers was synthesized. Within each layer of CdRe, the asymmetric [ReN(CN)4]21 units are arranged so that all nitrides are oriented in the same direction. Moreover, Cd ions also have an asymmetric coordination structure, with ethanol being bound axially on the nitride side, and water on the opposite side. Layers are then stacked in a head-to-head manner, defining a succession of hydrophilic and hydrophobic interlayer domains. CdRe exhibits anisotropic thermal expansion including in-plane negative and out-of-plane positive thermal expansion behavior, and shows green emission (em = 509 nm) originating from the metal-centered dd transition of [ReN(CN)4]21 units.

KW - Coordination polymer

KW - Luminescence

KW - Thermal expansion

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DO - 10.1246/cl.210244

M3 - Article

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SN - 0366-7022

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JO - Chemistry Letters

JF - Chemistry Letters

IS - 8

ER -

A cyanido-bridged luminescent coordination polymer composed of janus-type layers and its two-dimensional negative thermal expansion

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Keywords

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