A cubic dipole lattice of water molecules trapped inside carbon cages

Shinobu Aoyagi; Norihisa Hoshino; Tomoyuki Akutagawa; Yuki Sado; Ryo Kitaura; Hisanori Shinohara; Kunihisa Sugimoto; Rui Zhang; Yasujiro Murata

doi:10.1039/c3cc46683c

A cubic dipole lattice of water molecules trapped inside carbon cages

Shinobu Aoyagi, Norihisa Hoshino, Tomoyuki Akutagawa, Yuki Sado, Ryo Kitaura, Hisanori Shinohara, Kunihisa Sugimoto, Rui Zhang, Yasujiro Murata

Polymer Hybrid Materials Research Center

Research output: Contribution to journal › Article

25 Citations (Scopus)

Abstract

We report the crystal structure and dielectric properties of a pure H₂O@C₆₀ crystal at low temperature. The caged water molecules free from the hydrogen bonds rotate even at 8 K. The antifreeze rotating water molecules respond to an external electric field due to their permanent dipole moment.

Original language	English
Pages (from-to)	524-526
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	5
DOIs	https://doi.org/10.1039/c3cc46683c
Publication status	Published - 2014 Dec 10

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/c3cc46683c

Fingerprint Dive into the research topics of 'A cubic dipole lattice of water molecules trapped inside carbon cages'. Together they form a unique fingerprint.

Cite this

Aoyagi, S., Hoshino, N., Akutagawa, T., Sado, Y., Kitaura, R., Shinohara, H., Sugimoto, K., Zhang, R., & Murata, Y. (2014). A cubic dipole lattice of water molecules trapped inside carbon cages. Chemical Communications, 50(5), 524-526. https://doi.org/10.1039/c3cc46683c

@article{4f2e275d801b4837aeca368c7bc031d6,

title = "A cubic dipole lattice of water molecules trapped inside carbon cages",

abstract = "We report the crystal structure and dielectric properties of a pure H2O@C60 crystal at low temperature. The caged water molecules free from the hydrogen bonds rotate even at 8 K. The antifreeze rotating water molecules respond to an external electric field due to their permanent dipole moment.",

author = "Shinobu Aoyagi and Norihisa Hoshino and Tomoyuki Akutagawa and Yuki Sado and Ryo Kitaura and Hisanori Shinohara and Kunihisa Sugimoto and Rui Zhang and Yasujiro Murata",

year = "2014",

month = dec,

day = "10",

doi = "10.1039/c3cc46683c",

language = "English",

volume = "50",

pages = "524--526",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "5",

}

TY - JOUR

T1 - A cubic dipole lattice of water molecules trapped inside carbon cages

AU - Aoyagi, Shinobu

AU - Hoshino, Norihisa

AU - Akutagawa, Tomoyuki

AU - Sado, Yuki

AU - Kitaura, Ryo

AU - Shinohara, Hisanori

AU - Sugimoto, Kunihisa

AU - Zhang, Rui

AU - Murata, Yasujiro

PY - 2014/12/10

Y1 - 2014/12/10

N2 - We report the crystal structure and dielectric properties of a pure H2O@C60 crystal at low temperature. The caged water molecules free from the hydrogen bonds rotate even at 8 K. The antifreeze rotating water molecules respond to an external electric field due to their permanent dipole moment.

AB - We report the crystal structure and dielectric properties of a pure H2O@C60 crystal at low temperature. The caged water molecules free from the hydrogen bonds rotate even at 8 K. The antifreeze rotating water molecules respond to an external electric field due to their permanent dipole moment.

UR - http://www.scopus.com/inward/record.url?scp=84890415629&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84890415629&partnerID=8YFLogxK

U2 - 10.1039/c3cc46683c

DO - 10.1039/c3cc46683c

M3 - Article

AN - SCOPUS:84890415629

VL - 50

SP - 524

EP - 526

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 5

ER -