TY - JOUR
T1 - A Cu-added Zr-Ce-Sn-Pr-O mixed oxide phase with a high oxygen storage capacity
AU - Murota, Tadatoshi
AU - Sogawa, Kosuke
AU - Otsuka-Yao-Matsuo, Shinya
AU - Omata, Takahisa
PY - 2009
Y1 - 2009
N2 - Phases, oxygen release and absorption behaviour was investigated for Zr-Ce-Sn-Pr-O mixed oxides (Zr2/8Cex/8Sn y/8Pr(6-x-y)/8)O2-z (x=1.5, 4.5, y=0.5) together with the effect of Cu addition. Major phases of Sn-added samples were similar to those of Sn-free (Zr2/8Cex/8Pr (6-x)/8)O2-z phases, that is, CaF2-like λ and C phases for Pr-rich and Ce-rich compounds, respectively. All samples contained a SnO2 or a Sn phase. When Cu was added, repetitive oxidation and reduction appeared to promote the fine dissolution of Sn and Cu through bulk phases. OSC values of both (Zr2/8Ce 1.5/8Sn0.5/8Pr4/8)O2-z and (Zr 2/8Ce4.5/8Sn0.5/8Pr1/8)O 2-z were larger than those of the corresponding Sn-free samples. For the Ce-rich sample, Cu addition improved both the OSC value and its on-set temperature.
AB - Phases, oxygen release and absorption behaviour was investigated for Zr-Ce-Sn-Pr-O mixed oxides (Zr2/8Cex/8Sn y/8Pr(6-x-y)/8)O2-z (x=1.5, 4.5, y=0.5) together with the effect of Cu addition. Major phases of Sn-added samples were similar to those of Sn-free (Zr2/8Cex/8Pr (6-x)/8)O2-z phases, that is, CaF2-like λ and C phases for Pr-rich and Ce-rich compounds, respectively. All samples contained a SnO2 or a Sn phase. When Cu was added, repetitive oxidation and reduction appeared to promote the fine dissolution of Sn and Cu through bulk phases. OSC values of both (Zr2/8Ce 1.5/8Sn0.5/8Pr4/8)O2-z and (Zr 2/8Ce4.5/8Sn0.5/8Pr1/8)O 2-z were larger than those of the corresponding Sn-free samples. For the Ce-rich sample, Cu addition improved both the OSC value and its on-set temperature.
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U2 - 10.1088/1742-6596/165/1/012090
DO - 10.1088/1742-6596/165/1/012090
M3 - Article
AN - SCOPUS:67650996971
SN - 1742-6588
VL - 165
JO - Journal of Physics: Conference Series
JF - Journal of Physics: Conference Series
M1 - 012090
ER -