A convenient new route from diphosphene to 1,3-diphospha-allene and dynamic NMR studies of the 2,4,6-tri-t-butylphenyl derivative

Masaaki Yoshifuji; Shigeru Sasaki; Takashi Niitsu; Naoki Inamoto

doi:10.1016/S0040-4039(00)95155-4

A convenient new route from diphosphene to 1,3-diphospha-allene and dynamic NMR studies of the 2,4,6-tri-t-butylphenyl derivative

Masaaki Yoshifuji, Shigeru Sasaki, Takashi Niitsu, Naoki Inamoto

Research output: Contribution to journal › Article › peer-review

44 Citations (Scopus)

Abstract

Addition of dihalocarbenes to a diphosphene gave diphosphiranes which undergo rearrangement on treatment with alkyllithium reagents to afford 1,3-diphospha-allene; dynamic NMR studies on the allene are described.

Original language	English
Pages (from-to)	187-188
Number of pages	2
Journal	Tetrahedron Letters
Volume	30
Issue number	2
DOIs	https://doi.org/10.1016/S0040-4039(00)95155-4
Publication status	Published - 1989
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

Access to Document

10.1016/S0040-4039(00)95155-4

Cite this

@article{33d6c5b9a54045859c1109c9171850d8,

title = "A convenient new route from diphosphene to 1,3-diphospha-allene and dynamic NMR studies of the 2,4,6-tri-t-butylphenyl derivative",

abstract = "Addition of dihalocarbenes to a diphosphene gave diphosphiranes which undergo rearrangement on treatment with alkyllithium reagents to afford 1,3-diphospha-allene; dynamic NMR studies on the allene are described.",

author = "Masaaki Yoshifuji and Shigeru Sasaki and Takashi Niitsu and Naoki Inamoto",

year = "1989",

doi = "10.1016/S0040-4039(00)95155-4",

language = "English",

volume = "30",

pages = "187--188",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "2",

}

TY - JOUR

T1 - A convenient new route from diphosphene to 1,3-diphospha-allene and dynamic NMR studies of the 2,4,6-tri-t-butylphenyl derivative

AU - Yoshifuji, Masaaki

AU - Sasaki, Shigeru

AU - Niitsu, Takashi

AU - Inamoto, Naoki

PY - 1989

Y1 - 1989

N2 - Addition of dihalocarbenes to a diphosphene gave diphosphiranes which undergo rearrangement on treatment with alkyllithium reagents to afford 1,3-diphospha-allene; dynamic NMR studies on the allene are described.

AB - Addition of dihalocarbenes to a diphosphene gave diphosphiranes which undergo rearrangement on treatment with alkyllithium reagents to afford 1,3-diphospha-allene; dynamic NMR studies on the allene are described.

UR - http://www.scopus.com/inward/record.url?scp=0001280790&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0001280790&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(00)95155-4

DO - 10.1016/S0040-4039(00)95155-4

M3 - Article

AN - SCOPUS:0001280790

VL - 30

SP - 187

EP - 188

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 2

ER -

A convenient new route from diphosphene to 1,3-diphospha-allene and dynamic NMR studies of the 2,4,6-tri-t-butylphenyl derivative

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this