A convenient new route from diphosphene to 1,3-diphospha-allene and dynamic NMR studies of the 2,4,6-tri-t-butylphenyl derivative

Masaaki Yoshifuji, Shigeru Sasaki, Takashi Niitsu, Naoki Inamoto

Research output: Contribution to journalArticlepeer-review

43 Citations (Scopus)

Abstract

Addition of dihalocarbenes to a diphosphene gave diphosphiranes which undergo rearrangement on treatment with alkyllithium reagents to afford 1,3-diphospha-allene; dynamic NMR studies on the allene are described.

Original languageEnglish
Pages (from-to)187-188
Number of pages2
JournalTetrahedron Letters
Volume30
Issue number2
DOIs
Publication statusPublished - 1989 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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