A convenient new route from diphosphene to 1,3-diphospha-allene and dynamic NMR studies of the 2,4,6-tri-t-butylphenyl derivative

Masaaki Yoshifuji; Shigeru Sasaki; Takashi Niitsu; Naoki Inamoto

doi:10.1016/S0040-4039(00)95155-4

A convenient new route from diphosphene to 1,3-diphospha-allene and dynamic NMR studies of the 2,4,6-tri-t-butylphenyl derivative

Masaaki Yoshifuji, Shigeru Sasaki, Takashi Niitsu, Naoki Inamoto

Research output: Contribution to journal › Article › peer-review

42 Citations (Scopus)

Abstract

Addition of dihalocarbenes to a diphosphene gave diphosphiranes which undergo rearrangement on treatment with alkyllithium reagents to afford 1,3-diphospha-allene; dynamic NMR studies on the allene are described.

Original language	English
Pages (from-to)	187-188
Number of pages	2
Journal	Tetrahedron Letters
Volume	30
Issue number	2
DOIs	https://doi.org/10.1016/S0040-4039(00)95155-4
Publication status	Published - 1989
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)95155-4

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title = "A convenient new route from diphosphene to 1,3-diphospha-allene and dynamic NMR studies of the 2,4,6-tri-t-butylphenyl derivative",

abstract = "Addition of dihalocarbenes to a diphosphene gave diphosphiranes which undergo rearrangement on treatment with alkyllithium reagents to afford 1,3-diphospha-allene; dynamic NMR studies on the allene are described.",

author = "Masaaki Yoshifuji and Shigeru Sasaki and Takashi Niitsu and Naoki Inamoto",

year = "1989",

doi = "10.1016/S0040-4039(00)95155-4",

language = "English",

volume = "30",

pages = "187--188",

journal = "Tetrahedron Letters",

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T1 - A convenient new route from diphosphene to 1,3-diphospha-allene and dynamic NMR studies of the 2,4,6-tri-t-butylphenyl derivative

AU - Yoshifuji, Masaaki

AU - Sasaki, Shigeru

AU - Niitsu, Takashi

AU - Inamoto, Naoki

PY - 1989

Y1 - 1989

N2 - Addition of dihalocarbenes to a diphosphene gave diphosphiranes which undergo rearrangement on treatment with alkyllithium reagents to afford 1,3-diphospha-allene; dynamic NMR studies on the allene are described.

AB - Addition of dihalocarbenes to a diphosphene gave diphosphiranes which undergo rearrangement on treatment with alkyllithium reagents to afford 1,3-diphospha-allene; dynamic NMR studies on the allene are described.

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U2 - 10.1016/S0040-4039(00)95155-4

DO - 10.1016/S0040-4039(00)95155-4

M3 - Article

AN - SCOPUS:0001280790

VL - 30

SP - 187

EP - 188

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 2

ER -

A convenient new route from diphosphene to 1,3-diphospha-allene and dynamic NMR studies of the 2,4,6-tri-t-butylphenyl derivative

Abstract

ASJC Scopus subject areas

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