A concise synthesis of the ab-ring fragment of (-)-gambierol

Haruhiko Fuwa; Kazuaki Hirota; Makoto Sasaki

doi:10.3987/COM-12-S(N)21

A concise synthesis of the ab-ring fragment of (-)-gambierol

Haruhiko Fuwa, Kazuaki Hirota, Makoto Sasaki

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

We describe herein a concise synthesis of the AB-ring fragment of gambierol, wherein silver(I) trifluoromethanesulfonate-catalyzed 6-endo cyclization of a hydroxy ynone was exploited for the formation of the A-ring.

Original language	English
Pages (from-to)	127-132
Number of pages	6
Journal	Heterocycles
Volume	86
Issue number	1
DOIs	https://doi.org/10.3987/COM-12-S(N)21
Publication status	Published - 2012

ASJC Scopus subject areas

Analytical Chemistry
Pharmacology
Organic Chemistry

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title = "A concise synthesis of the ab-ring fragment of (-)-gambierol",

abstract = "We describe herein a concise synthesis of the AB-ring fragment of gambierol, wherein silver(I) trifluoromethanesulfonate-catalyzed 6-endo cyclization of a hydroxy ynone was exploited for the formation of the A-ring.",

author = "Haruhiko Fuwa and Kazuaki Hirota and Makoto Sasaki",

year = "2012",

doi = "10.3987/COM-12-S(N)21",

language = "English",

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pages = "127--132",

journal = "Heterocycles",

issn = "0385-5414",

publisher = "Japan Institute of Heterocyclic Chemistry",

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AU - Fuwa, Haruhiko

AU - Hirota, Kazuaki

AU - Sasaki, Makoto

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Y1 - 2012

N2 - We describe herein a concise synthesis of the AB-ring fragment of gambierol, wherein silver(I) trifluoromethanesulfonate-catalyzed 6-endo cyclization of a hydroxy ynone was exploited for the formation of the A-ring.

AB - We describe herein a concise synthesis of the AB-ring fragment of gambierol, wherein silver(I) trifluoromethanesulfonate-catalyzed 6-endo cyclization of a hydroxy ynone was exploited for the formation of the A-ring.

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U2 - 10.3987/COM-12-S(N)21

DO - 10.3987/COM-12-S(N)21

M3 - Article

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EP - 132

JO - Heterocycles

JF - Heterocycles

SN - 0385-5414

IS - 1

ER -

A concise synthesis of the ab-ring fragment of (-)-gambierol

Abstract

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