A comparison of the hot atom reaction with the implantation reaction in metallocene and its cyclodextrin inclusion compounds

H. Matsue, I. Yamaguchi, T. Sekine, K. Yoshihara

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

By comparing implantation reactions with hot atom reactions in ruthenocene derivatives and their β-cyclodextrin inclusion compounds, collision cascade enhancement of the parent yield was confirmed. From the product distribution among MCp2, MCpCp′, MCp′2 and others, geminate recombination, substitution and random recombination processes were estimated. The former two processes were sensitive to recoil energy, while no definite energy dependence was found in the last process. A prominent decrease of the yield by inclusion was detected for all the ruthenocene derivatives, indicating that normal reactions in these compounds were evidently restricted in the cavity of cyclodextrin.

Original languageEnglish
Pages (from-to)97-102
Number of pages6
JournalNuclear Inst. and Methods in Physics Research, B
Volume91
Issue number1-4
DOIs
Publication statusPublished - 1994 Jun 1

ASJC Scopus subject areas

  • Nuclear and High Energy Physics
  • Instrumentation

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