TY - JOUR
T1 - A comparison of the hot atom reaction with the implantation reaction in metallocene and its cyclodextrin inclusion compounds
AU - Matsue, H.
AU - Yamaguchi, I.
AU - Sekine, T.
AU - Yoshihara, K.
PY - 1994/6/1
Y1 - 1994/6/1
N2 - By comparing implantation reactions with hot atom reactions in ruthenocene derivatives and their β-cyclodextrin inclusion compounds, collision cascade enhancement of the parent yield was confirmed. From the product distribution among MCp2, MCpCp′, MCp′2 and others, geminate recombination, substitution and random recombination processes were estimated. The former two processes were sensitive to recoil energy, while no definite energy dependence was found in the last process. A prominent decrease of the yield by inclusion was detected for all the ruthenocene derivatives, indicating that normal reactions in these compounds were evidently restricted in the cavity of cyclodextrin.
AB - By comparing implantation reactions with hot atom reactions in ruthenocene derivatives and their β-cyclodextrin inclusion compounds, collision cascade enhancement of the parent yield was confirmed. From the product distribution among MCp2, MCpCp′, MCp′2 and others, geminate recombination, substitution and random recombination processes were estimated. The former two processes were sensitive to recoil energy, while no definite energy dependence was found in the last process. A prominent decrease of the yield by inclusion was detected for all the ruthenocene derivatives, indicating that normal reactions in these compounds were evidently restricted in the cavity of cyclodextrin.
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U2 - 10.1016/0168-583X(94)96198-0
DO - 10.1016/0168-583X(94)96198-0
M3 - Article
AN - SCOPUS:1542529598
SN - 0168-583X
VL - 91
SP - 97
EP - 102
JO - Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms
JF - Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms
IS - 1-4
ER -