A comparative study of different solvothermal methods for the synthesis of Sn2+-doped BaTiO3 powders and their dielectric properties

Yahong Xie, Shu Yin, Takatoshi Hashimoto, Yuichi Tokano, Atsushi Sasaki, Tsugio Sato

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)

Abstract

Ternary oxides containing Sn2+ are rare and difficult to prepare by the conventional solid state reactions due to the disproportionation of Sn2+ to Sn4+ and Sn at high temperatures. In this article, Sn2+-doped barium titanate, Ba1-x Sn x TiO3 (x = 0.00, 0.02, 0.05, and 0.10) nanopowders were successfully synthesized at a moderate temperature by a microwave-assisted solvothermal reaction (MSR) and a solvothermal reaction with rolling (SRR). The powders obtained using the MSR and SRR consisted of nanoparticles of 20-50 nm and 100-120 nm in diameter, respectively. The dielectric constant of the sample increased by doping with a small amount of Sn2+ (x 0.05), but decreased by doping in excess amounts of it.

Original languageEnglish
Pages (from-to)725-732
Number of pages8
JournalJournal of Materials Science
Volume45
Issue number3
DOIs
Publication statusPublished - 2010 Feb

ASJC Scopus subject areas

  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering

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