Abstract
A novel charge-disproportionation state with δ = 0.75 was observed in an electron-donor (D)/-acceptor (A) Dδ+2A2δ- layered framework by chemically tuning the electron-donating affinity of D at the boundary between D0.5+2A- and D+2A2- phases, which was pressure-sensitive due to the formation of the D+2A2- oxidation state.
Original language | English |
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Pages (from-to) | 7795-7798 |
Number of pages | 4 |
Journal | Chemical Communications |
Volume | 51 |
Issue number | 37 |
DOIs | |
Publication status | Published - 2015 May 7 |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry