A charge-disproportionate ordered state with δ = 0.75 in a chemically sensitive donor/acceptor Dδ+2A2δ- layered framework

Hiroki Fukunaga, Takafumi Yoshino, Hajime Sagayama, Jun Ichi Yamaura, Taka Hisa Arima, Wataru Kosaka, Hitoshi Miyasaka

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18 Citations (Scopus)

Abstract

A novel charge-disproportionation state with δ = 0.75 was observed in an electron-donor (D)/-acceptor (A) Dδ+2A2δ- layered framework by chemically tuning the electron-donating affinity of D at the boundary between D0.5+2A- and D+2A2- phases, which was pressure-sensitive due to the formation of the D+2A2- oxidation state.

Original languageEnglish
Pages (from-to)7795-7798
Number of pages4
JournalChemical Communications
Volume51
Issue number37
DOIs
Publication statusPublished - 2015 May 7

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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