A charge-disproportionate ordered state with δ = 0.75 in a chemically sensitive donor/acceptor Dδ+2A2δ- layered framework

Hiroki Fukunaga; Takafumi Yoshino; Hajime Sagayama; Jun Ichi Yamaura; Taka Hisa Arima; Wataru Kosaka; Hitoshi Miyasaka

doi:10.1039/c5cc01633a

A charge-disproportionate ordered state with δ = 0.75 in a chemically sensitive donor/acceptor D^δ+₂A^2δ- layered framework

Hiroki Fukunaga, Takafumi Yoshino, Hajime Sagayama, Jun Ichi Yamaura, Taka Hisa Arima, Wataru Kosaka, Hitoshi Miyasaka

Materials Development Division

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

A novel charge-disproportionation state with δ = 0.75 was observed in an electron-donor (D)/-acceptor (A) D^δ+₂A^2δ- layered framework by chemically tuning the electron-donating affinity of D at the boundary between D^0.5+₂A^- and D⁺₂A^2- phases, which was pressure-sensitive due to the formation of the D⁺₂A^2- oxidation state.

Original language	English
Pages (from-to)	7795-7798
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	37
DOIs	https://doi.org/10.1039/c5cc01633a
Publication status	Published - 2015 May 7

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "A novel charge-disproportionation state with δ = 0.75 was observed in an electron-donor (D)/-acceptor (A) Dδ+2A2δ- layered framework by chemically tuning the electron-donating affinity of D at the boundary between D0.5+2A- and D+2A2- phases, which was pressure-sensitive due to the formation of the D+2A2- oxidation state.",

author = "Hiroki Fukunaga and Takafumi Yoshino and Hajime Sagayama and Yamaura, {Jun Ichi} and Arima, {Taka Hisa} and Wataru Kosaka and Hitoshi Miyasaka",

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AU - Fukunaga, Hiroki

AU - Yoshino, Takafumi

AU - Sagayama, Hajime

AU - Yamaura, Jun Ichi

AU - Arima, Taka Hisa

AU - Kosaka, Wataru

AU - Miyasaka, Hitoshi

PY - 2015/5/7

Y1 - 2015/5/7

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AB - A novel charge-disproportionation state with δ = 0.75 was observed in an electron-donor (D)/-acceptor (A) Dδ+2A2δ- layered framework by chemically tuning the electron-donating affinity of D at the boundary between D0.5+2A- and D+2A2- phases, which was pressure-sensitive due to the formation of the D+2A2- oxidation state.

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A charge-disproportionate ordered state with δ = 0.75 in a chemically sensitive donor/acceptor D^δ+₂A^2δ- layered framework

Abstract

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