9-azanoradamantane N-Oxyl (Nor-AZADO): A highly active organocatalyst for alcohol oxidation

Masaki Hayashi, Yusuke Sasano, Shota Nagasawa, Masatoshi Shibuya, Yoshiharu Iwabuchi

Research output: Contribution to journalArticlepeer-review

48 Citations (Scopus)

Abstract

A highly active organocatalyst for alcohol oxidation has been developed. 9-Azanoradamantane N-oxyl (Nor-AZADO 4), constituting an unhindered, stable nitroxyl radical, exhibits superior catalytic activity to 2,2,6,6- tetramethylpiperidine-1-oxyl (TEMPO) and AZADOs in the oxidation of alcohols to their corresponding carbonyl compounds.

Original languageEnglish
Pages (from-to)1570-1573
Number of pages4
JournalChemical and Pharmaceutical Bulletin
Volume59
Issue number12
DOIs
Publication statusPublished - 2011

Keywords

  • 2-azaadamantane N-oxyl AZADO
  • Aerobic oxidation
  • Alcohol oxidation
  • Nitroxyl radical
  • Organocatalyst

ASJC Scopus subject areas

  • Chemistry(all)
  • Drug Discovery

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