@article{b60078ad0e62473c9834a3ac0b33ecc1,
title = "4-Chloro-2-azaadamantane N-Oxyl (4-Cl-AZADO): A Readily Preparable Organocatalyst for NOx Co-catalyzed Aerobic Alcohol Oxidation",
abstract = "Concise synthesis and structure-activity relationships study of 4-substituted 2-azaadamantane N-oxyls reveals that 4-chloro-2-azaadamantane N-oxyl (4-Cl-AZADO) is an efficient organocatalyst toward the aerobic oxidation of alcohols in the presence of NOx as a co-catalyst. The organocatalyst was easily synthesized from 2-adamantanone in five steps, and it showed high activity compared with many previously reported nitroxyl radical catalysts.",
keywords = "Alcohol, Organocatalysis, Oxidation, Radicals, Synthetic method",
author = "Shota Nagasawa and Yusuke Sasano and Yoshiharu Iwabuchi",
note = "Funding Information: This work was partly supported by a Grant‐in‐Aid for Scientific Research (B) (JSPS KAKENHI Grants JP22H02739 to Y.I.) and for Early‐Career Scientists (JSPS KAKENHI Grants JP21K15218 to S.N.) from JSPS, a Grant‐in‐Aid for Transformative Research Areas (A) Digitalization‐Driven Transformative Organic Synthesis (Digi‐TOS) (MEXT KAKENHI Grants JP21H05210 to Y.S.) from MEXT, and by the Platform Project for Supporting Drug Discovery and Life Science Research [Basis for Supporting Innovative Drug Discovery and Life Science Research (BINDS)] (Grant Number JP22ama121040j0001 to Y.I.) from AMED. Publisher Copyright: {\textcopyright} 2023 Wiley-VCH GmbH.",
year = "2023",
doi = "10.1002/ajoc.202300031",
language = "English",
journal = "Asian Journal of Organic Chemistry",
issn = "2193-5807",
publisher = "Wiley - VCH Verlag GmbH & CO. KGaA",
}