3-methyl-4-oxa-5-azahomoadamantane: Alkoxyamine-type organocatalyst for alcohol oxidation

Yusuke Sasano, Keiichi Murakami, Tomohiro Nishiyama, Eunsang Kwon, Yoshiharu Iwabuchi

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Strong, silent type: A novel alkoxyamine-type organocatalyst has been discovered for alcohol oxidation (see scheme). The alkoxyamine exhibits a high catalytic activity for the oxidation of alcohols to afford the corresponding carbonyl compounds in high yield by oxidative transformation into an oxoammonium ion, which is proposed to serve as an active species.

Original languageEnglish
Pages (from-to)12624-12627
Number of pages4
JournalAngewandte Chemie - International Edition
Volume52
Issue number48
DOIs
Publication statusPublished - 2013 Nov 25

Keywords

  • N-oxides
  • alcohols
  • organocatalysis
  • oxidation
  • synthetic methods

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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