(3-fluoro-4-methoxyanilinium)+([18]crown-6) supramolecular cation salt of ferromagnetic MnIICrIII(oxalate) 3]-

Toru Endo, Kazuya Kubo, Masashi Yoshitake, Shin Ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

A single crystal of (3-fluoro-4-methoxyanilinium)+([18]- crown-6)[MnIICrIII(oxalate)3] -(CH3OH)2 had the space group Cc owing to the arrangement of the 3-fluoro-4-methoxyanilinium+ cation with C1 symmetry and, therefore, was pyroelectric. A ferromagnetic transition at 5.5K was observed, which originated from the two-dimensional honeycomb structure of the [MnIICrIII(oxalate) 3]- anion.

Original languageEnglish
Pages (from-to)137-139
Number of pages3
JournalChemistry Letters
Volume42
Issue number2
DOIs
Publication statusPublished - 2013 Jan 31

ASJC Scopus subject areas

  • Chemistry(all)

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