2,4-Di-tert-butyl-6-piperidinophenyl as a sterically and electronically stabilizing group and X-ray analysis of the corresponding diselenoxophosphorane

Masaaki Yoshifuji, Shinya Sangu, Kazunori Kamijo, Kozo Toyota

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

The 2,4-di-tert-butyl-6-(1-piperidino)phenyl group is utilized to stabilize diselenoxophosphorane and the structure determined by X-ray analysis indicates coordination of the nitrogen lone-pair to the P-atom to form a four-membered ring with a remarkably distorted P-C-C bond angle.

Original languageEnglish
Pages (from-to)297-298
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number3
DOIs
Publication statusPublished - 1995 Dec 1

ASJC Scopus subject areas

  • Molecular Medicine

Fingerprint Dive into the research topics of '2,4-Di-tert-butyl-6-piperidinophenyl as a sterically and electronically stabilizing group and X-ray analysis of the corresponding diselenoxophosphorane'. Together they form a unique fingerprint.

  • Cite this