1,8-Diiodoanthracene

Waka Nakanishi; Shunpei Hitosugi; Anna Piskareva; Hiroyuki Isobe

doi:10.1107/S1600536810035191

1,8-Diiodoanthracene

Waka Nakanishi, Shunpei Hitosugi, Anna Piskareva, Hiroyuki Isobe

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The molecule of the title compound, C₁₄H₈I ₂, an inter-mediate in the synthesis of organic materials, is nearly planar, the maximum deviation from the mean plane being 0.032 (1) Å for the C atoms and 0.082 (2) Å for the I atoms. In the crystal structure, a sandwich-herringbone arrangement of molecules is observed, whereas a columnar π-stacking arrangement has been reported for the chlorinated congener 1,8-dichloro-anthracene. Similar effects of halogen substituents on the modulation of packing arrangements are reported for halogenated aromatic compounds such as tetra-cenes and chrycenes.

Original language	English
Pages (from-to)	o2515
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	10
DOIs	https://doi.org/10.1107/S1600536810035191
Publication status	Published - 2010 Oct

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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abstract = "The molecule of the title compound, C14H8I 2, an inter-mediate in the synthesis of organic materials, is nearly planar, the maximum deviation from the mean plane being 0.032 (1) {\AA} for the C atoms and 0.082 (2) {\AA} for the I atoms. In the crystal structure, a sandwich-herringbone arrangement of molecules is observed, whereas a columnar π-stacking arrangement has been reported for the chlorinated congener 1,8-dichloro-anthracene. Similar effects of halogen substituents on the modulation of packing arrangements are reported for halogenated aromatic compounds such as tetra-cenes and chrycenes.",

author = "Waka Nakanishi and Shunpei Hitosugi and Anna Piskareva and Hiroyuki Isobe",

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T1 - 1,8-Diiodoanthracene

AU - Nakanishi, Waka

AU - Hitosugi, Shunpei

AU - Piskareva, Anna

AU - Isobe, Hiroyuki

PY - 2010/10

Y1 - 2010/10

N2 - The molecule of the title compound, C14H8I 2, an inter-mediate in the synthesis of organic materials, is nearly planar, the maximum deviation from the mean plane being 0.032 (1) Å for the C atoms and 0.082 (2) Å for the I atoms. In the crystal structure, a sandwich-herringbone arrangement of molecules is observed, whereas a columnar π-stacking arrangement has been reported for the chlorinated congener 1,8-dichloro-anthracene. Similar effects of halogen substituents on the modulation of packing arrangements are reported for halogenated aromatic compounds such as tetra-cenes and chrycenes.

AB - The molecule of the title compound, C14H8I 2, an inter-mediate in the synthesis of organic materials, is nearly planar, the maximum deviation from the mean plane being 0.032 (1) Å for the C atoms and 0.082 (2) Å for the I atoms. In the crystal structure, a sandwich-herringbone arrangement of molecules is observed, whereas a columnar π-stacking arrangement has been reported for the chlorinated congener 1,8-dichloro-anthracene. Similar effects of halogen substituents on the modulation of packing arrangements are reported for halogenated aromatic compounds such as tetra-cenes and chrycenes.

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