η2-Co-ordination in a 1,3-diphospha-allene complex of platinum(0). Synthesis and solution 31P N.M.R. spectrum of [Pt(PPh3)2(RP=C=PR)] (R = 2,4,6-But 3C6H2)

Clara Afiong Akpan, Mohamed F. Meidine, John F. Nixon, Masaaki Yoshifuji, Kozo Toyota, Naoki Inamoto

Research output: Contribution to journalArticlepeer-review

21 Citations (Scopus)

Abstract

The first example of a co-ordination complex containing the novel diphospha-allene ligand RP=C=PR (R = 2,4,6-But3C 6H2) is reported and solution 31P n.m.r. studies indicate that in solution the ligand is bonded in an η2-fashion to the metal as in the isoelectronic allene and CS2 (or CO2) complexes.

Original languageEnglish
Pages (from-to)946-947
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number14
DOIs
Publication statusPublished - 1985 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Molecular Medicine

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